Publications

33) Wasielewski, M., Forbes, M., Frank, N., Kowalski, K., Scholes, G., Yuen-Zhou, J., Baldo, M., Freedman, D., Goldsmith, R., Goodson, T., Kirk, M., McCusker, J., Ogilvie, J., Shultz, D., Stoll, S., and Whaley , B. “Exploiting Chemistry and Chemical Systems for Quantum Information Science” Nat. Rev. Chem. (2020) 4, 490-504 (2020). DOI: 10.1038/s41570-020-0200-5

32) Garcia, J; Addison, JB; Liu, SZ; Lu, S; Faulkner, AL; Hodur, BM; Balmond, EI; Or, VW; Yun, JH; Trevino, K; Shen, BW; Shaw, JT; Frank, NL; Louie, AY “Antioxidant Sensing by Spiropyrans: Substituent Effects and NMR Spectroscopic Studies” J. Phys. Chem B. (2019) 123 (31), 6799-6809, DOI: 10.1021/acs.jpcb.9b03424

31) Paquette, M. M.; Plaul, D.; Patrick, B.; Kurimoto, A.; Frank, N. L.  “Opto-Spintronics: Photoisomerization-Induced Spin State Switching at 300 K in Photochrome-Cobalt Dioxolene Thin Films” J. Am. Chem. Soc. (2018) 140, 14990−15000. DOI: 10.1021/jacs.8b09190 (Highlighted as JACS Spotlight)

30) Jenkins, A.; Mao, Z.; Kurimoto, A.; Mix, L. T.; Frank, N.; Larsen, D. “Ultrafast Spintronics: Dynamics of the Photoisomerization-Induced Spin-Charge Excited State (PISCES) Mechanism in Spirooxazine-Based Photomagnetic Materials” J Phys Chem Lett. (2018) 9 (18) 5351-5357. doi: 10.1021/acs.jpclett.8b02166.

29) Zhang, X.; Kurimoto, A.; Frank, N. L.; Harbron, E. J.  “Controlling Photoswitching via pcFRET Conjugated Polymer Nanoparticles”  Phys. Chem C. (2018) 122 (39) 22728−22737 (Featured as ACS Editor’s Choice), DOI: 10.1021/acs.jpcc.8b06900

28) Plaul, D., Paquette, M. M., Kurimoto, A.,  and Frank*, N. L., “Bistable Complexes and Devices and Methods of Making and Using the Same”.U.S. CIP Application Filed; U.S. Patent Application No. 15/881,371 filed on January 26, 2018.

27) Zhang, X. Z.; Chamberlayne, C. F.; Kurimoto, A; Frank, N. L.; Harbron, EJ “Visible light photoswitching of conjugated polymer nanoparticle fluorescence” Chem. Commun. (2016) 52, (22) 4144-4147, DOI: 10.1039/c6cc00001k.

26) Plaul, D., Paquette, M. M., Kurimoto, A.,  and Frank*, N. L., “Magnetically Bistable Complexes And Devices And Methods Of Making And Using The Same” International Patent Application No. PCT/CA2016/050892 filed on July 28, 2016.

25) Copley, G.; Gillmore, J. G.; Crisman, J.; Kodis, G.; Gray, C. L.; Cherry, B. R.; Sherman, B. D.; Liddell, P. A.; Paquette, M. M.; Kelbauskas, L.; Frank, N. L.; Moore, A. L.; Moore, T. A.; Gust, D. “Modulating short wavelength fluorescence with long wavelength light” J. Am. Chem. Soc. (2014) 136, 34, 11994-12003 (AUG 27 2014). DOI: 10.1021/ja504879p

24) Frank, N. L.; Plaul, D.; Paquette, M. M.; Patrick, B.O. “Photoswitching the magnetization in photochromic metal complex thin films at room temperature” Conference: 246th National Meeting of the American-Chemical-Society (ACS) Location: Indianapolis, IN Date: SEP 08-12, 2013 Abstracts of Papers of the American Chemical Society 2013 246, Meeting Abstract: 327-INOR (SEP 8 2013).

23) Christou, G.; Blackman, A. G.; Perlepes, S. P.; Frank, N. L. Special Issue 100th Anniversary of the Award of the 1913 Nobel Prize in Chemistry to Alfred Werner: A Celebration-Preface Polyhedron  2013 52   Special Issue: SI   Pages: 1-2 (MAR 22 2013). DOI: 10.1016/j.poly.2013.01.013

22) Paquette, M. M.; Patrick, B. O.; Frank,* N.L. “Determining the Magnitude and Direction of Photoinduced Ligand Field Switching in Photochromic Metal–Organic Complexes: Molybdenum–Tetracarbonyl Spirooxazine Complexes” J. Am. Chem. Soc. 2011 133, 10081-10093 (JUL 6 2011). DOI: 10.1021/ja109776z

21) Yan, B.; McDonald, R.; Cramen, J.; Frank,* N. L. “Ferromagnetic Spin-Delocalized Electron Donors for Multifunctional Materials: π-Conjugated Benzotriazinyl Radicals” Chem. Comm. 2011 47, 11, 3201-3203 (MAR 21 2011). DOI: 10.1039/c0cc04727a

20) Patel, D. G., Paquette M. E., Kopelman, R. A., Kaminsky, W., Ferguson, M. J., Frank, * N. L. “Solution and Solid State Investigation of Medium Effects on Charge Separation in Metastable Photomerocyanines” J. Am. Chem. Soc. 2010 132,12568-12586 (SEP 15 2010). DOI: 10.1021/0100238h

19) Paquette, Michelle M.; Patrick, Brian O.; Frank, Natia L. “Using molybdenum tetracarbonyl complexes to investigate photoinduced ligand field switching in photochromic spirooxazine ligands” Abstracts of Papers of the American Chemical Society, 2010 240, Meeting Abstract: 684-INOR (AUG 22 2010)

18) Bowles, S. E.; Dooley, B. M.; Benedict, J. B.; Kaminsky, W.; Frank*, N. L. “The Competing Roles of Topology and Spin Density in the Magnetic Behavior of Spin Delocalized Radicals: Donor-Acceptor Annelated Nitronyl Nitroxides” Polyhedron 2009 28, Special Issue-SI, 1704-1709 (JUN 22 2009). DOI: 10.1016/j.poly.2008.10.056

17) Paquette, M. E.; Kopelman, R. A.; Beitler, E. B.; Frank*, N. L. “Incorporating Optical Bistability into a Magnetically Bistable System: A Photochromic Redox Isomeric Complex” Chem. Comm. 2009 36, 5424-5426 (Sep 28 2009). DOI: 10.1039/b911091g

16) Kopelman, R. A.; Paquette, M. M.; Frank, N. L. “Photoprocesses and magnetic behavior of photochromic transition metal indoline[phenanthrolinospirooxazine] complexes: Tunable photochromic materials”. Inorg. Chim. Acta  2008 361, (12-13) Special Issue-SI, 3570-3576. Invited Submission in Honor of Dante Gatteschi, (SEP 1 2008). DOI: 10.1016/j.ica.2008.03.079

15) Dooley, B. M.; Bowles, S. E.; Storr, T.; Frank*, N. L. Synthesis of Neutral Spin-Delocalized Electron Acceptors for Multifunctional Materials Org. Lett. 2007 9, 4781-4783 (NOV 8 2007). DOI: 10.1021/ol701725r

GaussView TIFF output

14) Robertson, C. M.; Myles, D. J. T.; Leitch, A. A.; Reed, R. W.; Dooley, B. M.; Frank, N. L.; Dube, P. A.; Thompson, L. K.; and Oakley,* R. T. Ferromagnetism in a Heavy Atom Heterocyclic Conductor J. Am. Chem. Soc. 2007129, 12688-12689 (OCT 24 2007). DOI: 10.1021/ja076841o

13) Patel, D. G.; Benedict, J. B.; Kopleman, R. A.; and Frank*, N. L. Photochromism of a Spirooxazine in the Single Crystalline Phase Chem. Comm. 2005 17, 2208-2210. DOI: 10.1039/b417026a

12) Kopelman, R. A.; Snyder, S. M.; Frank*, N. L. Tunable Photochromism of Spirooxazines via Metal Complexation J. Am. Chem. Soc. 2003 125, 13684-13685 (NOV 12 2003) DOI: 10.1021/ja036306y.


Frank Postdoc and Grad Pubs

11) Wang, P; Miller, J. E.; Henling, L. M.; Stern, C. L.; Frank, N. L.; Eckermann, A. L.; Meade, T. J. Synthesis and Characterization of Ruthenium and Rhenium Nucleosides Inorg. Chem. 2007 46, 9853-9862 (NOV 12 2007). DOI: 10.1021/ic701250r

10) Frank, N. L.; Meade,* T. J. 5’ Modification Of Duplex DNA With A Ruthenium Electron Donor-Acceptor Pair Using Solid-Phase DNA Synthesis Inorg. Chem. 2003 42, 1039-1044. (FEB 24 2003) DOI: 10.1021/ic025567q

9) Krider, E. S.; Rack, J. J.; Frank, N. L. and Meade*, T. J. Automated Synthesis of 3′-Metalated Oligonucleotides Inorg. Chem. 2001 40, 4002-4009. (JUL 30 2001) DOI: 10.1021/ic010396v.

8) Frank, N. L.; Clérac, R.; Green, M. T.; Daro, N.; Sutter, J.-P.; Kahn*, O.; Coulon*, C.; Golhen, S. and Ouahab*, L. Synthesis, Crystal Structure, Magnetic, and Electron Paramagnetic Resonance Properties of a Spiroconjugated Biradical. Evidence for a Spiroconjugation Exchange Pathway J. Am. Chem. Soc. 2000 122, 2053-2061. (MAR 8 2000) DOI: 10.1021/ja993071a

7) Krider, E. S.; Rack, J. J.; Frank, N. L.; Meade, T. J. DNA-mediated electron transfer studies. Abstracts of Papers of the American Chemical Society 1999 217 , U1091-U1091, Part: 1. Meeting Abstract: 492-INOR (Mar 21 1999)

6) Frank, N. L.; Baldridge, K. K.; and Siegel, J. S. The effect of strained bicycloannelation on the structure and reactivity of benzene and pyridine. Abstracts of Papers of the American Chemical Society (1996) 211, 449-ORGN Part: 2 (MAR 24 1996)

5) Bürgi, H.-B.; Baldridge, K. K.; Hardcastle, K.; Frank, N. L., Siegel*, J. S., Ziller, J. X-ray Diffraction Evidence for a ‘Cyclohexatriene’ Motif in the Molecular Structure of Trisbicyclo[2.1.1]hexabenzene: Bond Alternation After the Refutation of the Mills-Nixon Theory Angew. Chem. Int. Ed. Engl. 1995 34, 1454-1456. (JUL 31 1995) DOI: 10.1002/anie.199514541

4) Frank, Natia L.; Baldridge, Kim K.; Gantzel, P.; and Siegel*, Jay S. Partial Bond Localization in The Crystal Structure of Trisbicyclo[2.2.1]heptabenzene and Its Effect on Cr-arene dynamics Tetrahedron Lett. 1995 36, 25, 4389-4392. (JUN 19 1995) DOI: 10.1016/0040-4039(95)00857-9

3) Venugopalan, P.; Bürgi, H.-B.; Frank, N. L.; Baldridge, K. K.; and Siegel,* J. S. The Crystal Structure of a Heptiptycene-Chlorobenzene Clathrate. Tetrahedron Lett. 1995 36, 14, 2419-2422. (APR 3 1995) DOI: 10.1016/0040-4039(95)00318-7

2) Frank, Natia L.; Baldridge, Kim K.; Siegel, Jay S.* The Synthesis and Characterization of Trisbicyclo [2.1.1] hexabenzene, a Highly Strained Bicycloannelated Benzene J. Am. Chem. Soc. 1995 117, 2102-2103. (Feb 22 1995) DOI: 10.1021/ja00112a028

1) Frank, N. L., Siegel,* J. S. Mills-Nixon Effects? (Review) In Advances in Theoretically Interesting Organic Molecules, Thummel, R. P., Ed.; JAI Press; Greenwich, 1995; Vol. 3; p. 209-260.

Antioxidant Sensing by Spiropyrans: Substituent Effects and NMR Spectroscopic Studies Garcia, J.; Addison, J. B.; Liu, S. J.;Lu, S.; Faulkner, A. L.; Hodur, B. M.; Balmond, E. I.; Or, V. W.; Yun, J. H.; Trevino, K. M.; Shen, B.;Shaw, J. T.; Frank, N. L.; Louie, A. Y. J. Phys. Chem. B (2019) 08 Jul 2019, https://doi.org/10.1021/acs.jpcb.9b03424

Opto-Spintronics: Photoisomerization-Induced Spin State Switching at 300 K in Photochrome-Cobalt Dioxolene Thin Films

Paquette, M. M.; Plaul, D.; Patrick, B.; Kurimoto, A.; Frank, N. L.  J. Am. Chem. Soc. (2018) 140, 14990−15000. (Highlighted as JACS Spotlight https://pubs.acs.org/doi/full/10.1021/jacs.8b11781).

Ultrafast Spintronics: Dynamics of the Photoisomerization-Induced Spin-Charge Excited State (PISCES) Mechanism in Spirooxazine-Based Photomagnetic Material

Jenkins, A.; Mao, Z.; Kurimoto, A.; Mix, L. T.; Frank, N.; Larsen, D. J. Phys. Chem Lett. (2018) 9, 5351−5357.

Controlling Photoswitching via pcFRET in Conjugated Polymer Nanoparticles

Zhang, X.; Kurimoto, A.; Frank, N. L.; Harbron, E.  J. Phys. Chem C. (2018) 122, 22728−22737. (Featured as ACS Editor’s Choice).

Visible Light Photoswitching Of Conjugated Polymer Nanoparticle Fluorescence

Xinzi Zhang, Christian F. Chamberlayne, Aiko Kurimoto, Natia L. Frank and Elizabeth J. Harbron, Chem. Commun., 2016, 52, 4144. 

Modulating short wavelength fluorescence with long wavelength light

Copley, G.; Gillmore, J. G.; Crisman, J.; Kodis, G.; Gray, C. L.; Cherry, B. R.; Sherman, B. D.; Liddell, P. A.; Paquette, M. M.; Kelbauskas, L.; Frank, N. L.; Moore, A. L.; Moore, T. A.; Gust, D. Modulating short wavelength fluorescence with long wavelength light J. Am. Chem. Soc. 2014 136, 34, 11994-12003 (AUG 27 2014). DOI: https://pubs.acs.org/doi/full/10.1021/ja504879p.

Special Issue 100th Anniversary of the Award of the 1913 Nobel Prize in Chemistry to Alfred Werner: A Celebration-Preface

Christou, G.; Blackman, A. G.; Perlepes, S. P.; Frank, N. L. Special Issue 100th Anniversary of the Award of the 1913 Nobel Prize in Chemistry to Alfred Werner: A Celebration-Preface Polyhedron  2013 52 Special Issue: SI, Pages: 1-2 (MAR 22 2013). DOI: https://pubs.acs.org/doi/full/10.1016/j.poly.2013.01.013.

Determining the Magnitude and Direction of Photoinduced Ligand Field Switching in Photochromic Metal-Organic Complexes: Molybdenum-Tetracarbonyl Spirooxazine Complexes

Paquette, M. M.; Patrick, B. O.; Frank,* N.L. Determining the Magnitude and Direction of Photoinduced Ligand Field Switching in Photochromic Metal–Organic Complexes: Molybdenum–Tetracarbonyl Spirooxazine Complexes J. Am. Chem. Soc. 2011 133, 10081-10093 (JUL 6 2011). DOI: https://pubs.acs.org/doi/full/10.1021/ja109776z.

Ferromagnetic spin-delocalized electron donors for multifunctional materials: pi-conjugated benzotriazinyl radicals

Yan, B.; McDonald, R.; Cramen, J.; Frank,* N. L. Ferromagnetic Spin-Delocalized Electron Donors for Multifunctional Materials: π-Conjugated Benzotriazinyl Radicals Chem. Comm. 2011 47, 11, 3201-3203 (MAR 21 2011). DOI: https://pubs.acs.org/doi/full/10.1039/c0cc04727a.

A Solution- and Solid-State Investigation of Medium Effects on Charge Separation in Metastable Photomerocyanines

Patel, D. G., Paquette M. E., Kopelman, R. A., Kaminsky, W., Ferguson, M. J., Frank, * N. L. Solution and Solid State Investigation of Medium Effects on Charge Separation in Metastable Photomerocyanines J. Am. Chem. Soc. 2010 132,12568-12586 (SEP 15 2010). DOI: https://pubs.acs.org/doi/full/10.1021/0100238h .

Using molybdenum tetracarbonyl complexes to investigate photoinduced ligand field switching in photochromic spirooxazine ligands

Paquette, Michelle M.; Patrick, Brian O.; Frank, Natia L. Using molybdenum tetracarbonyl complexes to investigate photoinduced ligand field switching in photochromic spirooxazine ligands Abstracts of Papers of the American Chemical Society2010 240, Meeting Abstract: 684-INOR (AUG 22 2010)

The competing roles of topology and spin density in the magnetic behavior of spin-delocalized radicals: Donor-acceptor annelated nitronyl nitroxides

Bowles, S. E.; Dooley, B. M.; Benedict, J. B.; Kaminsky, W.; Frank*, N. L. The Competing Roles of Topology and Spin Density in the Magnetic Behavior of Spin Delocalized Radicals: Donor-Acceptor Annelated Nitronyl Nitroxides  Polyhedron  2009 28, 9-10, 1704-1709 (JUN 22 2009). DOI: https://pubs.acs.org/doi/full/10.1016/j.poly.2008.10.056. (Conference: 11th International Conference on Molecule-Based Magnets (ICMM 2008) Location: Florence, ITALY Date: SEP 21-24, 2008)

Incorporating optical bistability into a magnetically bistable system: a photochromic redox isomeric complex

Paquette, M. E.; Kopelman, R. A.; Beitler, E. B.; Frank*, N. L. Incorporating Optical Bistability into a Magnetically Bistable System: A Photochromic Redox Isomeric Complex Chem. Comm. 2009 36, 5424-5426 (SEP 28 2009). DOI: https://pubs.acs.org/doi/full/10.1039/b911091g.

Photoprocesses and magnetic behavior of photochromic transition metal indoline[phenanthrolinospirooxazine] complexes: Tunable photochromic materials

Kopelman, R. A.; Paquette, M. M.; Frank, N. L. Photoprocesses and magnetic behavior of photochromic transition metal indoline[phenanthrolinospirooxazine] complexes: Tunable photochromic materials. Inorg. Chim. Acta  2008 361, (12-13) Special Issue-SI, 3570-3576. Invited Submission in Honor of Dante Gatteschi, (SEP 1 2008). DOI: https://pubs.acs.org/doi/full/10.1016/j.ica.2008.03.079.

Synthesis and characterization of ruthenium and rhenium nucleosides

Wang, P; Miller, J. E.; Henling, L. M.; Stern, C. L.; Frank, N. L.; Eckermann, A. L.; Meade, T. J. Synthesis and Characterization of Ruthenium and Rhenium Nucleosides Inorg. Chem. 2007 46, 9853-9862 (NOV 12 2007). DOI: https://pubs.acs.org/doi/full/10.1021/ic701250r.

Synthesis of neutral spin-delocalized electron acceptors for multifunctional materials

Dooley, B. M.; Bowles, S. E.; Storr, T.; Frank*, N. L. Synthesis of Neutral Spin-Delocalized Electron Acceptors for Multifunctional Materials Org. Lett. 2007 9, 4781-4783 (NOV 8 2007). DOI: https://pubs.acs.org/doi/full/10.1021/ol701725r.

Ferromagnetism in a heavy atom heterocyclic radical conductor

Robertson, C. M.; Myles, D. J. T.; Leitch, A. A.; Reed, R. W.; Dooley, B. M.; Frank, N. L.; Dube, P. A.; Thompson, L. K.; and Oakley,* R. T. Ferromagnetism in a Heavy Atom Heterocyclic Conductor J. Am. Chem. Soc. 2007 129, 12688-12689 (OCT 24 2007). DOI: https://pubs.acs.org/doi/full/10.1021/ja076841o.

Photochromism of a spirooxazine in the single crystalline phase

Patel, D. G.; Benedict, J. B.; Kopleman, R. A.; and Frank*, N. L. Photochromism of a Spirooxazine in the Single Crystalline Phase Chem. Comm. 2005 17, 2208-2210. DOI: https://pubs.acs.org/doi/full/10.1039/b417026a.

Tunable photochromism of spirooxazines via metal coordination

11) Kopelman, R. A.; Snyder, S. M.; Frank*, N. L. Tunable Photochromism of Spirooxazines via Metal Complexation J. Am. Chem. Soc. 2003 125, 13684-13685 (NOV 12 2003) DOI: https://pubs.acs.org/doi/full/10.1021/ja036306y.

5 ‘ modification of duplex DNA with a ruthenium electron donor-acceptor pair using solid-phase DNA synthesis

Frank, N. L.; Meade,* T. J. 5’ Modification Of Duplex DNA With A Ruthenium Electron Donor-Acceptor Pair Using Solid-Phase DNA Synthesis Inorg. Chem. 2003 42, 1039-1044. (FEB 24 2003) DOI: https://pubs.acs.org/doi/full/10.1021/ic025567q.

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