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34) COMMITTEE ON IDENTIFYING OPPORTUNITIES AT THE INTERFACE OF CHEMISTRY AND QUANTUM INFORMATION SCIENCE National Academies of Sciences, Engineering, and Medicine. 2023. Advancing Chemistry and Quantum Information Science: An Assessment of Research Opportunities at the Interface of Chemistry and Quantum Information Science in the United States. Washington, DC: The National Academies Press.
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33) Wasielewski, M., Forbes, M., Frank, N., Kowalski, K., Scholes, G., Yuen-Zhou, J., Baldo, M., Freedman, D., Goldsmith, R., Goodson, T., Kirk, M., McCusker, J., Ogilvie, J., Shultz, D., Stoll, S., and Whaley , B. “Exploiting Chemistry and Chemical Systems for Quantum Information Science” Nat. Rev. Chem. (2020) 4, 490-504 (2020).
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32) Garcia, J; Addison, JB; Liu, SZ; Lu, S; Faulkner, AL; Hodur, BM; Balmond, EI; Or, VW; Yun, JH; Trevino, K; Shen, BW; Shaw, JT; Frank, NL; Louie, AY “Antioxidant Sensing by Spiropyrans: Substituent Edects and NMR Spectroscopic Studies” J. Phys. Chem B. (2019) 123 (31), 6799-6809.
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31) Paquette, M. M.; Plaul, D.; Patrick, B.; Kurimoto, A.; Frank, N. L. “Opto- Spintronics: Photoisomerization-Induced Spin State Switching at 300 K in Photochrome-Cobalt Dioxolene Thin Films” J. Am. Chem. Soc. (2018) 140, 14990−15000.
DOI: doi.org/10.1021/jacs.8b09190 (Highlighted as JACS Spotlight)
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30) Jenkins, A.; Mao, Z.; Kurimoto, A.; Mix, L. T.; Frank, N.; Larsen, D. “Ultrafast Spintronics: Dynamics of the Photoisomerization-Induced Spin-Charge Excited State (PISCES) Mechanism in Spirooxazine-Based Photomagnetic Materials” J Phys Chem Lett. (2018) 9 (18) 5351-5357.
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29) Zhang, X.; Kurimoto, A.; Frank, N. L.; Harbron, E. J. “Controlling Photoswitching via pcFRET Conjugated Polymer Nanoparticles” Phys. Chem C. (2018) 122 (39) 22728−22737. (Featured as ACS Editor’s Choice)
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28) Plaul, D., Paquette, M. M., Kurimoto, A., and Frank*, N. L., “Bistable Complexes and Devices and Methods of Making and Using the Same”.U.S. CIP Application Filed; U.S. Patent Application No. 15/881,371 nled on January 26, 2018.
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27) Zhang, X. Z.; Chamberlayne, C. F.; Kurimoto, A; Frank, N. L.; Harbron, EJ “Visible light photoswitching of conjugated polymer nanoparticle ouorescence” Chem. Commun. (2016) 52, (22) 4144-4147,
DOI: 10.1039/c6cc00001k
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26) Plaul, D., Paquette, M. M., Kurimoto, A., and Frank*, N. L., “Magnetically Bistable Complexes And Devices And Methods Of Making And Using The Same” International Patent Application No. PCT/CA2016/050892 nled on July 28, 2016.
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25) Copley, G.; Gillmore, J. G.; Crisman, J.; Kodis, G.; Gray, C. L.; Cherry, B.R.; Sherman, B. D.; Liddell, P. A.; Paquette, M. M.; Kelbauskas, L.; Frank, N.L.; Moore, A. L.; Moore, T. A.; Gust, D. “Modulating short wavelength ouorescence with long wavelength light” J. Am. Chem. Soc. (2014) 136, 34, 11994- 12003 (AUG 27 2014).
DOI: 10.1021/ja504879p
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24) Frank, N. L.; Plaul, D.; Paquette, M. M.; Patrick, B.O. “Photoswitching the magnetization in photochromic metal complex thin nlms at room temperature” Conference: 246th National Meeting of the American-Chemical-Society (ACS) Location: Indianapolis, IN Date: SEP 08-12, 2013 Abstracts of Papers of the American Chemical Society 2013 246, Meeting Abstract: 327-INOR (SEP 8 2013).
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23) Christou, G.; Blackman, A. G.; Perlepes, S. P.; Frank, N. L. Special Issue 100th Anniversary of the Award of the 1913 Nobel Prize in Chemistry to Alfred Werner: A Celebration-Preface Polyhedron 2013 52 Special Issue: SI Pages: 1-2 (MAR 22 2013).
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22) Paquette, M. M.; Patrick, B. O.; Frank,* N.L. “Determining the Magnitude and Direction of Photoinduced Ligand Field Switching in Photochromic Metal– Organic Complexes: Molybdenum–Tetracarbonyl Spirooxazine Complexes” J. Am. Chem. Soc. 2011 133, 10081-10093 (JUL 6 2011).
DOI: 10.1021/ja109776z
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21) Yan, B.; McDonald, R.; Cramen, J.; Frank,* N. L. “Ferromagnetic Spin- Delocalized Electron Donors for Multifunctional Materials: π-Conjugated Benzotriazinyl Radicals” Chem. Comm. 2011 47, 11, 3201-3203 (MAR 21 2011).
DOI: 10.1039/c0cc04727a
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20) Patel, D. G., Paquette M. E., Kopelman, R. A., Kaminsky, W., Ferguson, M. J., Frank, * N. L. “A Solution- and Solid-State Investigation of Medium Effects on Charge Separation in Metastable Photomerocyanines” J. Am. Chem. Soc. 2010 132,12568-12586 (SEP 15 2010).
DOI: 10.1021/ja100238h
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19) Paquette, Michelle M.; Patrick, Brian O.; Frank, Natia L. “Using molybdenum tetracarbonyl complexes to investigate photoinduced ligand neld switching in photochromic spirooxazine ligands” Abstracts of Papers of the American Chemical Society, 2010 240, Meeting Abstract: 684-INOR (AUG 22 2010)
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18) Bowles, S. E.; Dooley, B. M.; Benedict, J. B.; Kaminsky, W.; Frank*, N. L. “The Competing Roles of Topology and Spin Density in the Magnetic Behavior of Spin Delocalized Radicals: Donor-Acceptor Annelated Nitronyl Nitroxides” Polyhedron 2009 28, Special Issue-SI, 1704-1709 (JUN 22 2009).
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17) Paquette, M. E.; Kopelman, R. A.; Beitler, E. B.; Frank*, N. L. “Incorporating Optical Bistability into a Magnetically Bistable System: A Photochromic Redox Isomeric Complex” Chem. Comm. 2009 36, 5424-5426 (Sep 28 2009).
DOI: 10.1039/b911091g
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16) Kopelman, R. A.; Paquette, M. M.; Frank, N. L. “Photoprocesses and magnetic behavior of photochromic transition metal indoline[phenanthrolinospirooxazine] complexes: Tunable photochromic materials”. Inorg. Chim. Acta 2008 361, (12-13) Special Issue-SI, 3570-3576. Invited Submission in Honor of Dante Gatteschi, (SEP 1 2008).
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15) Dooley, B. M.; Bowles, S. E.; Storr, T.; Frank*, N. L. “Synthesis of Neutral Spin- Delocalized Electron Acceptors for Multifunctional Materials” Org. Lett. 2007 9, 4781-4783 (NOV 8 2007).
DOI: 10.1021/ol701725r
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14) Robertson, C. M.; Myles, D. J. T.; Leitch, A. A.; Reed, R. W.; Dooley, B. M.; Frank, N. L.; Dube, P. A.; Thompson, L. K.; and Oakley,* R. T. “Ferromagnetism in a Heavy Atom Heterocyclic Conductor” J. Am. Chem. Soc. 2007129, 12688-12689 (OCT 24 2007).
DOI: 10.1021/ja076841o
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13) Patel, D. G.; Benedict, J. B.; Kopleman, R. A.; and Frank*, N. L. “Photochromism of a Spirooxazine in the Single Crystalline Phase” Chem. Comm. 2005 17, 2208- 2210.
DOI: 10.1039/b417026a
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12) Kopelman, R. A.; Snyder, S. M.; Frank*, N. L. “Tunable Photochromism of Spirooxazines via Metal Complexation” J. Am. Chem. Soc. 2003 125, 13684-13685 (NOV 12 2003)
DOI: 10.1021/ja036306y
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11) Wang, P; Miller, J. E.; Henling, L. M.; Stern, C. L.; Frank, N. L.; Eckermann, A. L.; Meade, T. J. “Synthesis and Characterization of Ruthenium and Rhenium Nucleosides” Inorg. Chem. 2007 46, 9853-9862 (NOV 12 2007).
DOI: 10.1021/ic701250r
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10) Frank, N. L.; Meade,* T. J. “5’ Modification Of Duplex DNA With A Ruthenium Electron Donor-Acceptor Pair Using Solid-Phase DNA Synthesis” Inorg. Chem. 2003 42, 1039-1044. (FEB 24 2003)
DOI: 10.1021/ic025567q
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9) Krider, E. S.; Rack, J. J.; Frank, N. L. and Meade*, T. J. “Automated Synthesis of 3′-Metalated Oligonucleotides” Inorg. Chem. 2001 40, 4002-4009. (JUL 30 2001)
DOI: 10.1021/ic010396v
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8) Frank, N. L.; Clérac, R.; Green, M. T.; Daro, N.; Sutter, J.-P.; Kahn, O.; Coulon, C.; Golhen, S. and Ouahab*, L. “Synthesis, Crystal Structure, Magnetic, and Electron Paramagnetic Resonance Properties of a Spiroconjugated Biradical. Evidence for a Spiroconjugation Exchange Pathway” J. Am. Chem. Soc. 2000 122, 2053-2061. (MAR 8 2000)
DOI: 10.1021/ja993071a
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7) Krider, E. S.; Rack, J. J.; Frank, N. L.; Meade, T. J. DNA-mediated electron transfer studies. Abstracts of Papers of the American Chemical Society 1999 217 , U1091-U1091, Part: 1. Meeting Abstract: 492-INOR (Mar 21 1999)
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6) Frank, N. L.; Baldridge, K. K.; and Siegel, J. S. The edect of strained bicycloannelation on the structure and reactivity of benzene and pyridine. Abstracts of Papers of the American Chemical Society (1996) 211, 449-ORGN Part: 2 (MAR 24 1996)
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5) Bürgi, H.-B.; Baldridge, K. K.; Hardcastle, K.; Frank, N. L., Siegel*, J. S., Ziller, J. “X-Ray Diffraction Evidence for a ‘Cyclohexatriene’ Motif in the Molecular Structure of Trisbicyclo[2.1.1]hexabenzene: Bond Alternation After the Refutation of the Mills-Nixon Theory” Angew. Chem. Int. Ed. Engl. 1995 34, 1454-1456. (JUL 31 1995)
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4) Frank, Natia L.; Baldridge, Kim K.; Gantzel, P.; and Siegel*, Jay S. “Partial Bond Localization in The Crystal Structure of Trisbicyclo[2.2.1]heptabenzene and Its Effect on Cr-arene Dynamics” Tetrahedron Lett. 1995 36, 25, 4389-4392. (JUN 19 1995)
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3) Venugopalan, P.; Bürgi, H.-B.; Frank, N. L.; Baldridge, K. K.; and Siegel,* J. S. “The Crystal Structure of a Heptiptycene-Chlorobenzene Clathrate”. Tetrahedron Lett. 1995 36, 14, 2419-2422. (APR 3 1995)
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2) Frank, Natia L.; Baldridge, Kim K.; Siegel, Jay S.* “The Synthesis and Characterization of Trisbicyclo[2.1.1]hexabenzene, a Highly Strained Bicycloannelated Benzene” J. Am. Chem. Soc. 1995 117, 2102-2103. (Feb 22 1995)
DOI: 10.1021/ja00112a028
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1) Frank, N. L., Siegel,* J. S. “Mills-Nixon Effects?” (Review) In Advances in Theoretically Interesting Organic Molecules, Thummel, R. P., Ed.; JAI Press; Greenwich, 1995; Vol. 3; p. 209-260.
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Antioxidant Sensing by Spiropyrans: Substituent EDects and NMR Spectroscopic Studies
Garcia, J.; Addison, J. B.; Liu, S. J.;Lu, S.; Faulkner, A. L.; Hodur, B. M.; Balmond, E. I.; Or, V. W.; Yun, J. H.; Trevino, K. M.; Shen, B.;Shaw, J. T.; Frank, N. L.; Louie, A. Y. J. Phys. Chem. B (2019) 08 Jul
2019, https://doi.org/10.1021/acs.jpcb.9b03424
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Opto-Spintronics: Photoisomerization-Induced Spin State Switching at 300 K in Photochrome-Cobalt Dioxolene Thin Films
Paquette, M. M.; Plaul, D.; Patrick, B.; Kurimoto, A.; Frank, N. L. J. Am. Chem. Soc. (2018) 140, 14990−15000. (Highlighted as JACS
Spotlight https://pubs.acs.org/doi/full/10.1021/jacs.8b11781).
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Ultrafast Spintronics: Dynamics of the Photoisomerization-Induced Spin- Charge Excited State (PISCES) Mechanism in Spirooxazine-Based Photomagnetic Material
Jenkins, A.; Mao, Z.; Kurimoto, A.; Mix, L. T.; Frank, N.; Larsen, D. J. Phys. Chem Lett. (2018) 9, 5351−5357.
-
Controlling Photoswitching via pcFRET in Conjugated Polymer Nanoparticles
Zhang, X.; Kurimoto, A.; Frank, N. L.; Harbron, E. J. Phys. Chem C. (2018) 122, 22728−22737. (Featured as ACS Editor’s Choice).
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Visible Light Photoswitching Of Conjugated Polymer Nanoparticle Fluorescence
Xinzi Zhang, Christian F. Chamberlayne, Aiko Kurimoto, Natia L. Frank and Elizabeth J. Harbron, Chem. Commun., 2016, 52, 4144.
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Modulating short wavelength uorescence with long wavelength light
Copley, G.; Gillmore, J. G.; Crisman, J.; Kodis, G.; Gray, C. L.; Cherry, B.
R.; Sherman, B. D.; Liddell, P. A.; Paquette, M. M.; Kelbauskas, L.; Frank, N.
L.; Moore, A. L.; Moore, T. A.; Gust, D. Modulating short wavelength ouorescence with long wavelength light J. Am. Chem. Soc. 2014 136, 34, 11994-12003 (AUG 27 2014). DOI: https://pubs.acs.org/doi/full/10.1021/ja504879p.
-
Special Issue 100th Anniversary of the Award of the 1913 Nobel Prize in Chemistry to Alfred Werner: A Celebration-Preface
Christou, G.; Blackman, A. G.; Perlepes, S. P.; Frank, N. L. Special Issue 100th Anniversary of the Award of the 1913 Nobel Prize in Chemistry to Alfred Werner: A Celebration-Preface Polyhedron 2013 52 Special Issue: SI, Pages: 1-2 (MAR 22 2013). DOI: https://pubs.acs.org/doi/full/10.1016/j.poly.2013.01.013.
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Determining the Magnitude and Direction of Photoinduced Ligand Field Switching in Photochromic Metal-Organic Complexes: Molybdenum- Tetracarbonyl Spirooxazine Complexes
Paquette, M. M.; Patrick, B. O.; Frank,* N.L. Determining the Magnitude and Direction of Photoinduced Ligand Field Switching in Photochromic Metal– Organic Complexes: Molybdenum–Tetracarbonyl Spirooxazine Complexes J. Am. Chem. Soc. 2011 133, 10081-10093 (JUL 6 2011).
DOI: https://pubs.acs.org/doi/full/10.1021/ja109776z.
-
Ferromagnetic spin-delocalized electron donors for multifunctional materials: pi-conjugated benzotriazinyl radicals
Yan, B.; McDonald, R.; Cramen, J.; Frank,* N. L. Ferromagnetic Spin-Delocalized Electron Donors for Multifunctional Materials: π-Conjugated Benzotriazinyl Radicals Chem. Comm. 2011 47, 11, 3201-3203 (MAR 21 2011).
DOI: https://pubs.acs.org/doi/full/10.1039/c0cc04727a.
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A Solution- and Solid-State Investigation of Medium EDects on Charge Separation in Metastable Photomerocyanines
Patel, D. G., Paquette M. E., Kopelman, R. A., Kaminsky, W., Ferguson, M. J., Frank, * N. L. Solution and Solid State Investigation of Medium Edects on Charge Separation in Metastable Photomerocyanines J. Am. Chem. Soc. 2010 132,12568- 12586 (SEP 15 2010). DOI: https://pubs.acs.org/doi/full/10.1021/0100238h .
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Using molybdenum tetracarbonyl complexes to investigate photoinduced ligand ^eld switching in photochromic spirooxazine ligands
Paquette, Michelle M.; Patrick, Brian O.; Frank, Natia L. Using molybdenum tetracarbonyl complexes to investigate photoinduced ligand neld switching in photochromic spirooxazine ligands Abstracts of Papers of the American Chemical Society, 2010 240, Meeting Abstract: 684-INOR (AUG 22 2010)
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The competing roles of topology and spin density in the magnetic behavior of spin-delocalized radicals: Donor-acceptor annelated nitronyl nitroxides
Bowles, S. E.; Dooley, B. M.; Benedict, J. B.; Kaminsky, W.; Frank*, N. L. The Competing Roles of Topology and Spin Density in the Magnetic Behavior of Spin Delocalized Radicals: Donor-Acceptor Annelated Nitronyl
Nitroxides Polyhedron 2009 28, 9-10, 1704-1709 (JUN 22 2009).
DOI: https://pubs.acs.org/doi/full/10.1016/j.poly.2008.10.056. (Conference: 11th I nternational Conference on Molecule-Based Magnets (ICMM 2008) Location: Florence, ITALY Date: SEP 21-24, 2008)
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Incorporating optical bistability into a magnetically bistable system: a photochromic redox isomeric complex
Paquette, M. E.; Kopelman, R. A.; Beitler, E. B.; Frank*, N. L. Incorporating Optical Bistability into a Magnetically Bistable System: A Photochromic Redox Isomeric Complex Chem. Comm. 2009 36, 5424-5426 (SEP 28
2009). DOI: https://pubs.acs.org/doi/full/10.1039/b911091g.
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Photoprocesses and magnetic behavior of photochromic transition metal indoline[phenanthrolinospirooxazine] complexes: Tunable photochromic materials
Kopelman, R. A.; Paquette, M. M.; Frank, N. L. Photoprocesses and magnetic behavior of photochromic transition metal indoline[phenanthrolinospirooxazine] complexes: Tunable photochromic materials. Inorg. Chim. Acta 2008 361, (12-13) Special Issue-SI, 3570-3576. Invited Submission in Honor of Dante Gatteschi, (SEP 1 2008).
DOI: https://pubs.acs.org/doi/full/10.1016/j.ica.2008.03.079.
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Synthesis and characterization of ruthenium and rhenium nucleosides
Wang, P; Miller, J. E.; Henling, L. M.; Stern, C. L.; Frank, N. L.; Eckermann, A. L.; Meade, T. J. Synthesis and Characterization of Ruthenium and Rhenium Nucleosides Inorg. Chem. 2007 46, 9853-9862 (NOV 12 2007).
DOI: https://pubs.acs.org/doi/full/10.1021/ic701250r.
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Synthesis of neutral spin-delocalized electron acceptors for multifunctional materials
Dooley, B. M.; Bowles, S. E.; Storr, T.; Frank*, N. L. Synthesis of Neutral Spin- Delocalized Electron Acceptors for Multifunctional Materials Org. Lett. 2007 9, 4781-4783 (NOV 8 2007). DOI: https://pubs.acs.org/doi/full/10.1021/ol701725r.
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Ferromagnetism in a heavy atom heterocyclic radical conductor
Robertson, C. M.; Myles, D. J. T.; Leitch, A. A.; Reed, R. W.; Dooley, B. M.; Frank, N. L.; Dube, P. A.; Thompson, L. K.; and Oakley,* R. T. Ferromagnetism in a Heavy Atom Heterocyclic Conductor J. Am. Chem. Soc. 2007 129, 12688-12689 (OCT 24 2007). DOI: https://pubs.acs.org/doi/full/10.1021/ja076841o.
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Photochromism of a spirooxazine in the single crystalline phase
Patel, D. G.; Benedict, J. B.; Kopleman, R. A.; and Frank*, N. L. Photochromism of a Spirooxazine in the Single Crystalline Phase Chem. Comm. 2005 17, 2208-2210. DOI: https://pubs.acs.org/doi/full/10.1039/b417026a.
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Tunable photochromism of spirooxazines via metal coordination
11) Kopelman, R. A.; Snyder, S. M.; Frank*, N. L. Tunable Photochromism of Spirooxazines via Metal Complexation J. Am. Chem. Soc. 2003 125, 13684-13685 (NOV 12 2003) DOI: https://pubs.acs.org/doi/full/10.1021/ja036306y.
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5 ‘ modifcation of duplex DNA with a ruthenium electron donor-acceptor pair using solid-phase DNA synthesis
Frank, N. L.; Meade,* T. J. 5’ Modincation Of Duplex DNA With A Ruthenium Electron Donor-Acceptor Pair Using Solid-Phase DNA Synthesis Inorg. Chem. 2003 42, 1039-1044. (FEB 24 2003)
DOI: https://pubs.acs.org/doi/full/10.1021/ic025567q.















![16) Kopelman, R. A.; Paquette, M. M.; Frank, N. L. “Photoprocesses and magnetic behavior of photochromic transition metal indoline[phenanthrolinospirooxazine] complexes: Tunable photochromic materials”. Inorg. Chim. Acta 2008 361, (12-13) Special Issue-SI, 3570-3576. Invited Submission in Honor of Dante Gatteschi, (SEP 1 2008).](https://thefranklab.com/wp-content/uploads/2021/07/toc.gif?w=1024)







![4) Frank, Natia L.; Baldridge, Kim K.; Gantzel, P.; and Siegel*, Jay S. “Partial Bond Localization in The Crystal Structure of Trisbicyclo[2.2.1]heptabenzene and Its Effect on Cr-arene Dynamics” Tetrahedron Lett. 1995 36, 25, 4389-4392. (JUN 19 1995)](https://thefranklab.com/wp-content/uploads/2023/04/pic4.gif?w=345)
